arXiv:2605.00245v1 Announce Type: new Abstract: Large language models (LLMs) are now being explored for defense applications that require reliable and legally compliant decision support. They also hold significant potential to enhance decision making, coordination, and operational efficiency in military contexts. These uses demand evaluation methods that reflect the doctrinal standards that guide real military operations. Existing safety benchmarks focus on general social risks and do not test whether models follow the legal and ethical rules that govern real military operations. To address this gap, we introduce ARMOR 2025, a military aligned safety benchmark grounded in three core military doctrines the Law of War, the Rules of Engagement, and the Joint Ethics Regulation. We extract doctrinal text from these sources and generate multiple choice questions that preserve the intended meaning of each rule. The benchmark is organized through a taxonomy informed by the Observe Orient Decide Act (OODA) decision making framework. This structure enables systematic testing of accuracy and refusal across military relevant decision types. This benchmark features a structured 12-category taxonomy, 519 doctrinally grounded prompts, and rigorous evaluation procedures applied to 21 commercial LLMs. Evaluation results reveal critical gaps in safety alignment for military applications.